The following is offered with all proper disclaimers.
In rare instance and under unusual circumstance the Dept of
Energy has permitted grant funds to be used to recruit a
scientist - when said scientist was to replace another who
was on the grant before leaving the institution.
More commonly grants are funded with salaries defined for
people yet to be recruited. In these cases, the costs of
recruitment are not covered by the grant, but the future
salary of the newly recruited is included.